We propose a new programme of research which will provide substantial and important advances in our understanding of the physics of energetic electron transport and shock breakout uniformity in dense plasma - processes critical to the success of Inertial Confinement Fusion (ICF) schemes. We will do this by developing an entirely new class of diagnostic, based on ion emission, and apply this to diagnose electron transport and shock uniformity breakout with unprecedented micron-scale resolution. This offers significant advantages over existing diagnostic techniques and when combined with existing techniques will greatly increase our understanding of key physical processes for ICF.ICF holds the promise of achieving conditions in the laboratory where more energy is produced in fusion reactions than is incident on an imploding fusion pellet, thus creating an energy source (Inertial Fusion Energy). A critical issue for the fast ignition approach to ICF is the efficient delivery of energy from a short 'ignition' laser pulse, usually by acceleration and transport of energetic electrons. An understanding of energy transport and heating by laser-accelerated relativistic electrons is therefore of fundamental importance to the fast ignitor concept and yet there are many outstanding physics questions relating to this. The transport of fast electrons through dense matter is also important for the development of high power laser driven ion sources. The research proposed here involves a comprehensive programme of experimental investigations, underpinned by theoretical modelling, designed to address questions on electron transport and shock propagation of fundamental importance to the development of laser driven particle and radiation sources in general and ICF in particular.The programme will be carried out using state-of-the-art high intensity laser systems at the Central Laser Facility, Rutherford Appleton Laboratory.