Title
Nanostructure in Functional Ceramics

CoPED ID
baab8b29-a5cc-4188-98d6-173c100aef91

Status
Closed

Funders

Value
£1,213,690

Start Date
Sept. 30, 2007

End Date
March 30, 2011

Description

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The functional properties of many ceramics are controlled principally by displacements of ions which create small electric dipoles across the unit cells of certain types of oxides. However, in order for these electric dipoles to affect the bulk properties, they must be cooperative, i.e. the displacemetns must occur in the same direction for at least several tens of unit cells. Functional properties are tailored for a specific application by modifying the direction and length over which the dipoles are cooperative as well as the temperature at which they occur (Tc). In ceramic capacitors which act as rf filters, a mesoscale heterogeneous distribution of dopants modifies the magnitude, direction and onset temperature of the dipoles, preventing the filter frequency from changing significantly with temperature. In piezoelectric ceramics, a nanoscale mixture of monoclinic, tetragonal and rhombohedral phases in which the direction/magnitude of the dipoles differs in each structure, optimises the charge/displacement produced. This programme aims to investigate the local nanostructure of ceramics using advanced analystical instrumentation and determine its relation to bulk properties (permittivity, dielectric loss, piezoelectricity). This understanding will be used to improve performance and develop new functional ceramics.

Ian Reaney PI_PER
W Rainforth COI_PER
Derek Sinclair COI_PER

Subjects by relevance
  1. Ceramics
  2. Nanostructures
  3. Ions
  4. Optimisation
  5. Properties

Extracted key phrases
  1. Functional property
  2. New functional ceramic
  3. Small electric dipole
  4. Bulk property
  5. Functional Ceramics
  6. Nanostructure
  7. Ceramic capacitor
  8. Piezoelectric ceramic
  9. Unit cell
  10. Direction
  11. Onset temperature
  12. Rf filter
  13. Filter frequency
  14. Mesoscale heterogeneous distribution
  15. Advanced analystical instrumentation

Related Pages

UKRI project entry

UK Project Locations
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