High capacity mixed metal borohydrides ammoniates for hydrogen energy storage applications

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Title
High capacity mixed metal borohydrides ammoniates for hydrogen energy storage applications

CoPED ID
620028cb-a622-468d-8bf0-3ea04d0815a9

Status
Active

Funders

Value
No funds listed.

Start Date
Sept. 30, 2019

End Date
Dec. 30, 2023

Description

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Hydrogen is a promising alternative energy carrier for the future due to its high specific energy and environmental friendliness. The development of hydrogen storage technologies to support renewable energy systems and low-carbon transportation is important. Currently, high pressure compressed hydrogen gas (700 bar) is used for vehicles, however they are very costly and achieve low energy densities. Many light weight hydrides, such as LiBH4 and LiAlH4, although having high storage capacities have major drawbacks of irreversibility and high working temperatures. Ammonia can be catalytically split in to N2 and H2 and its hydrogen content is about 17.3 wt.%, which can store 30 % more energy per volume than liquid H2. Utilization of NH3 for on-board storage system is hampered due to its toxicity. In recent years, a new class of materials called Metal Borohydride Ammoniates (MBAs) show improved hydrogen storage properties. MBAs tend to release hydrogen/ammonia gas at more practical temperatures and with greater purity. This research will focus on the development of novel Mixed Metal Borohydride Ammoniates (MMBAs) to achieve even higher hydrogen storage densities, elucidate the reaction mechanisms responsible for the decomposition process and investigate catalysts to accelerate the release of hydrogen from these materials. The project involves synthesis of various MMBAs, a variety of material characterisation techniques (e.g. XRD, TGA, DSC, FTIR, GC-MS) and hydrogen performance testing by the Sieverts' technique. There will also be opportunities to use large scale facilities such as neutron diffraction experiments at Institut Laue Langevin in France.

Gavin Walker SUPER_PER
Jacob Prosser STUDENT_PER

Subjects by relevance
  1. Hydrogen
  2. Fuel cells
  3. Renewable energy sources
  4. Warehousing

Extracted key phrases
  1. High hydrogen storage density
  2. High capacity mixed metal borohydride ammoniate
  3. Hydrogen energy storage application
  4. High storage capacity
  5. High specific energy
  6. Hydrogen storage technology
  7. Hydrogen storage property
  8. High working temperature
  9. High pressure
  10. Promising alternative energy carrier
  11. Low energy density
  12. Renewable energy system
  13. Hydrogen gas
  14. Hydrogen performance testing
  15. Board storage system

Related Pages

UKRI project entry

UK Project Locations